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Review on cellulose paper-based electrodes for sustainable batteries with high energy densities

《化学科学与工程前沿（英文）》 2023年 第17卷 第8期   页码 1010-1027 doi: 10.1007/s11705-023-2307-y

摘要： Powering the future, while maintaining strong socioeconomic growth and a cleaner environment, is going to be one of the biggest challenges faced by mankind nowadays. Thus, there is a transition from the use of fossil fuels to renewable energy sources. Cellulose, the main component of paper, represents a unique type of bio-based building blocks featuring exciting properties: low-cost, hierarchical fibrous structures, hydrophilicity, biocompatible, mechanical flexibility, and renewability, which make it perfect for use in paper-based sustainable energy storage devices. This review focuses on lithium-ion battery application of celluloses with cellulose at different scales, i.e., cellulose microfibers, and nanocellulose, and highlights the new trends in the field. Recent advances and approaches to construct high mass loading paper electrodes toward high energy density batteries are evaluated and the limitations of paper-based cathodes are discussed. This will stimulate the use of natural resources and thereby the development of renewable electric energy systems based on sustainable technologies with low environmental impacts and carbon footprints.

关键词： cellulose     paper electrodes     Li-ion batteries     high energy density    

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Cutting performance of surgical electrodes by constructing bionic microstriped structures

《机械工程前沿（英文）》 2023年 第18卷 第1期 doi: 10.1007/s11465-022-0728-9

摘要： Surgical electrodes rely on thermal effect of high-frequency current and are a widely used medical tool for cutting and coagulating biological tissue. However, tissue adhesion on the electrode surface and thermal injury to adjacent tissue are serious problems in surgery that can affect cutting performance. A bionic microstriped structure mimicking a banana leaf was constructed on the electrode via nanosecond laser surface texturing, followed by silanization treatment, to enhance lyophobicity. The effect of initial, simple grid-textured, and bionic electrodes with different wettabilities on tissue adhesion and thermal injury were investigated using horizontal and vertical cutting modes. Results showed that the bionic electrode with high lyophobicity can effectively reduce tissue adhesion mass and thermal injury depth/area compared with the initial electrode. The formation mechanism of adhered tissue was discussed in terms of morphological features, and the potential mechanism for antiadhesion and heat dissipation of the bionic electrode was revealed. Furthermore, we evaluated the influence of groove depth on tissue adhesion and thermal injury and then verified the antiadhesion stability of the bionic electrode. This study demonstrates a promising approach for improving the cutting performance of surgical electrodes.

关键词： surgical electrodes     tissue adhesion     thermal injury     bionic structures     cutting performance     medical tools    

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Hollow-fiber gas penetration electrodes efficiently produce renewable synthetic fuels

《能源前沿（英文）》 2022年 第16卷 第5期   页码 700-705 doi: 10.1007/s11708-022-0842-8

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Research progress on low dielectric constant modification of cellulose insulating paper for power transformers

《化学科学与工程前沿（英文）》 2023年 第17卷 第8期   页码 991-1009 doi: 10.1007/s11705-022-2259-7

摘要： Because of the increase in the transmission voltage levels, the demand for insulation reliability of power transformers has increasingly become critical. Cellulose insulating paper is the main insulating component of power transformers. To improve the insulation level of ultrahigh voltage transformers and reduce their weight and size, reducing the dielectric constant of oil-immersed cellulose insulating paper is highly desired. Cellulose is used to produce power-transformer insulating papers owing to its excellent electrical properties, renewability, biodegradability and abundance. The dielectric constant of a cellulose insulating paper can be effectively reduced by chemical or physical modification. This study presents an overview of the foreign and domestic research status of the use of modification technology to reduce the dielectric constant of cellulose insulating papers. All the mentioned methods are analyzed in this study. Finally, some recommendations for future modified cellulose insulating paper research and applications are proposed. This paper can provide a reference for further research on low dielectric constant cellulose insulating paper in the future.

关键词： low dielectric constant     chemical and physical modification     cellulose insulating paper     transformer     nanomaterials.    

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Technical measures to achieve a cleaner production mode for recycled paper mills

Chao HE, Zhaolin GU, Shucheng YANG, Jidong LIANG, Weina DAI, Yanling HE

《环境科学与工程前沿（英文）》 2010年 第4卷 第4期   页码 466-474 doi: 10.1007/s11783-010-0242-x

摘要： China’s paper production reached 79.8 ×10 t in 2008 and ranked number one in the world. Because of its high consumption of water, energy and materials and its serious pollution, the present processes are not likely to be sustainable. An alternative, the closed Water Loop-Papermaking Integration (WLPI) method, is put forward in this paper. The WLPI method can be realized in a recycled paper mill by adding technologies and using recycled water. Many industrial case studies have shown that a large quantity of water, energy and materials can be saved, and the quantity of waste sludge and wastewater discharge was minimized by using the WLPI method. The design of the water reuse system, control of calcium hardness, water recycling and minimal waste sludge are discussed. Anaerobic technology plays an important role in the WLPI method to lower cost, energy use and waste. In the brown paper and coated white board production, zero-effluent discharge can be realized. Fresh water consumption is only 1–2 m ·t . For the paper mills with deinking and bleaching processes, about 10 m ·t of fresh water and a similar amount of effluent discharge are needed. Power saving using anaerobic technology is 70% when recycled water is used in comparison with the conventional activated sludge process. Waste sludge can be decreased to about 5% of the initial process due to reuse of the waste sludge and the lower bio-sludge production of the anaerobic process.

关键词： water reuse     zero discharge     anaerobic treatment     recycled paper     cleaner production    

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Investigation of electrochemical degradation and application of e-paper dyes in organic solvents

Luhai LI, Ming WANG, Yi FANG, Shunan QIAO

《化学科学与工程前沿（英文）》 2009年 第3卷 第2期   页码 182-185 doi: 10.1007/s11705-009-0062-3

摘要： To avoid environmental pollution due to organic dye solutions, the electrophoresis and degradation of dye in organic solvents such as alcohol were investigated. Many dyes were tested in the Indium tin oxide (ITO) electrode driving cell, and about 15 dyes moved under voltage driving. Both the curves of ultraviolet-visible (UV-Vis) and infrared (IR) spectra of the electrophoresis samples showed that the metal complexes Red 04 and Acid Black 1 were degradable in alcohol solution by electrochemical reaction. The cyclic volt-ampere curves of the samples from the electrochemical working station proved that electrochemical reactions took place. Based on the analysis of UV-Vis and IR spectra, the electrochemical degradation products of azo and metal complex azo dyes at lower voltage driving (1-5 V) in organic solvents are oxidized azobenzene, not hydrazine, which was found in the electrochemical degradation of dye water solutions. When the ITO electrode is modified by a polyimide (PI) film to a thickness less than 4 μm, the electrochemical degradation of the dye in alcohol solution will not appear in the cyclic volt-ampere curves. A dye electrophoresis in organic solution flexible prototype e-paper display was formed and the display picture is shown.

关键词： electrochemical degradation     electrophoresis     e-paper     oxidized azobenzene group    

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Easily-manufactured paper-based materials with high porosity for adsorption/separation applications in

《化学科学与工程前沿（英文）》 2023年 第17卷 第7期   页码 830-839 doi: 10.1007/s11705-022-2267-7

摘要： A multi-functional porous paper-based material was prepared from grass pulp by simple pore-forming and green cross-linking method. As a pore-forming agent, calcium citrate increased the porosity of the paper-based material from 30% to 69% while retaining the mechanical strength. The covalent cross-linking of citric acid between cellulose fibers improved both the wet strength and adsorption capacity. In addition, owing to the introduction of high-content carboxyl groups as well as the construction of hierarchical micro-nano structure, the underwater oil contact angle was up to 165°. The separation efficiency of the emulsified oil was 99.3%, and the water flux was up to 2020 L·m–2·h–1. The theoretical maximum adsorption capacities of cadmium ion, lead ion and methylene blue reached 136, 229 and 128.9 mg·g–1, respectively. The continuous purification of complex wastewater can be achieved by using paper-based materials combined with filtration technology. This work provides a simple, low cost and environmental approach for the treatment of complex wastewater containing insoluble oil, organic dyes, and heavy metal ions.

关键词： adsorption     oil–water separation     underwater superoleophobicity     wastewater treatment    

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Ultrafast-laser-treated poly(3,4-ethylenedioxythiophene): poly(styrenesulfonate) electrodes with enhanced

《化学科学与工程前沿（英文）》 2023年 第17卷 第2期   页码 206-216 doi: 10.1007/s11705-022-2203-x

摘要： Poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) is an important organic electrode for solution-processed low-cost electronic devices. However, it requires doping and post-solvent treatment to improve its conductivity, and the chemicals used for such treatments may affect the device fabrication process. In this study, we developed a novel route for exploiting ultrafast lasers (femtosecond and picosecond laser) to simultaneously enhance the conductivity and transparency of PEDOT:PSS films and fabricate patterned solution-processed electrodes for electronic devices. The conductivity of the PEDOT:PSS film was improved by three orders of magnitude (from 3.1 to 1024 S·cm–1), and high transparency of up to 88.5% (average visible transmittance, AVT) was achieved. Raman and depth-profiling X-ray photoelectron spectroscopy revealed that the oxidation level of PEDOT was enhanced, thereby increasing the carrier concentration. The surface PSS content also decreased, which is beneficial to the carrier mobility, resulting in significantly enhanced electrical conductivity. Further, we fabricated semitransparent perovskite solar cells using the as-made PEDOT:PSS as the transparent top electrodes, and a power conversion efficiency of 7.39% was achieved with 22.63% AVT. Thus, the proposed route for synthesizing conductive and transparent electrodes is promising for vacuum and doping-free electronics.

关键词： PEDOT:PSS     ultrafast laser     transparent electrode     ST-PSCs     patterning    

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论文演化图：学术文献多视角结构化检索 None

Dan-ping LIAO, Yun-tao QIAN

《信息与电子工程前沿（英文）》 2019年 第20卷 第2期   页码 187-205 doi: 10.1631/FITEE.1700105

摘要： 学术文献检索关注于选取最可能符合用户信息需求的论文。目前大部分检索系统局限于输出相关文献列表，而这些检出文献相互独立。本文旨在揭示检索结果的相互关系。提出一种为学术文献建立结构化检索结果的方法，称为论文演化图（PEG）。PEG采用多个演化链描述查询输入信息在不同主题方向的演化情况。通过论文作者、参考文献引用、论文内容信息这3个视角，PEG能够发现文献之间各种潜在关系，并多视角展示文献演化过程。该文献检索系统支持关键词、单篇论文、双论文3种查询方式。PEG构造主要有3个步骤：首先，采用元图分解法把文献软聚合为多个群落，获取每篇论文的主题分布；其次，从与查询相关的文献群落中提取主题连贯性演化链。每条演化链反映查询信息的某一视角；最后，提取的演化链组合形成论文演化图，可以覆盖查询涉及的所有主题。基于真实文献数据库的实验结果表明，该方法能够建立对用户有意义的论文演化图。

关键词： 论文演化图；学术文献检索；元图分解；主题连贯性    

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Efficient photoelectrochemical oxidation of rhodamine B on metal electrodes without photocatalyst or

Xuejiao Wang, Xiang Feng, Jing Shang

《环境科学与工程前沿（英文）》 2018年 第12卷 第6期 doi: 10.1007/s11783-018-1061-8

摘要：

•The efficient PEC degradation of RhB is realized using no photocatalyst.

•The efficient PEC degradation of RhB features the low salinity.

•The PEC degradation of RhB takes place on the anode and cathode simultaneously.

关键词： Energy relay structure     Energy saving     Photocatalyst-free and low-salinity degradation     Photoelectrochemical cell    

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Electrospun porous carbon nanofibers derived from bio-based phenolic resins as free-standing electrodes

《化学科学与工程前沿（英文）》 2023年 第17卷 第5期   页码 504-515 doi: 10.1007/s11705-022-2260-1

摘要： Phenolic resins were employed to prepare electrospun porous carbon nanofibers with a high specific surface area as free-standing electrodes for high-performance supercapacitors. However, the sustainable development of conventional phenolic resin has been challenged by petroleum-based phenol and formaldehyde. Lignin with abundant phenolic hydroxyl groups is the main non-petroleum resource that can provide renewable aromatic compounds. Hence, lignin, phenol, and furfural were used to synthesize bio-based phenolic resins, and the activated carbon nanofibers were obtained by electrospinning and one-step carbonization activation. Fourier transform infrared and differential scanning calorimetry were used to characterize the structural and thermal properties. The results reveal that the apparent activation energy of the curing reaction is 89.21 kJ·mol–1 and the reaction order is 0.78. The activated carbon nanofibers show a uniform diameter, specific surface area up to 1100 m2·g–1, and total pore volume of 0.62 cm3·g–1. The electrode demonstrates a specific capacitance of 238 F·g–1 (0.1 A·g–1) and good rate capability. The symmetric supercapacitor yields a high energy density of 26.39 W·h·kg–1 at 100 W·kg–1 and an excellent capacitance retention of 98% after 10000 cycles. These results confirm that the activated carbon nanofiber from bio-based phenolic resins can be applied as electrode material for high-performance supercapacitors.

关键词： lignin     bio-based phenolic resins     electrospinning     activated carbon nanofibers     supercapacitors    

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Performance of activated carbon coated graphite bipolar electrodes on capacitive deionization method

Hossein D. Atoufi, Hasti Hasheminejad, David J. Lampert

《环境科学与工程前沿（英文）》 2020年 第14卷 第6期 doi: 10.1007/s11783-020-1278-1

摘要： Abstract • Graphite bipolar electrodes act as an appropriate bed for the CDI process. • Activated carbon Coating improves the application of the electrodes. • CDI is an environmentally friendly method to apply for brackish water. • Initial concentration is the most important parameter in the CDI method. • CDI process in a batch-mode setup needs more development. This research investigates a capacitive deionization method for salinity reduction in a batch reactor as a new approach for desalination. Reductions of cost and energy compared with conventional desalination methods are the significant advantages of this approach. In this research, experiments were performed with a pair of graphite bipolar electrodes that were coated with a one-gram activated carbon solution. After completing preliminary tests, the impacts of four parameters on electrical conductivity reduction, including (1) the initial concentration of feed solution, (2) the duration of the tests, (3) the applied voltage, and (4) the pH of the solution, were examined. The results show that the maximum efficiency of electrical conductivity reduction in this laboratory-scale reactor is about 55%. Furthermore, the effects of the initial concentration of feed solution are more significant than the other parameters. Thus, using the capacitive deionization method for water desalination with low and moderate salt concentrations (i.e., brackish water) is proposed as an affordable method. Compared with conventional desalination methods, capacitive deionization is not only more efficient but also potentially more environmentally friendly.

关键词： Capacitive deionization (CDI)     Desalination     Electrical conductivity (EC)     Graphite bipolar electrode     Activated carbon coated (ACC)    

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Self-supported transition metal phosphide based electrodes as high-efficient water splitting cathodes

Yan Zhang, Jian Xiao, Qiying Lv, Shuai Wang

《化学科学与工程前沿（英文）》 2018年 第12卷 第3期   页码 494-508 doi: 10.1007/s11705-018-1732-9

摘要：

Electrolytic water splitting has been considered as a promising technology to produce highly pure H2 by using electrical power produced from wind, solar energy or other fitful renewable energy resources. Combining novel self-supporting structure and high-performance transition metal phosphides (TMP) shows substantial promise for practical application in water splitting. In this review, we try to provide a comprehensive analysis of the design and fabrication of various self-supported TMP electrodes for hydrogen evolution reaction, which are divided into three categories: catalysts growing on carbon-based substrates, catalysts growing on metal-based substrates and freestanding catalyst films. The material structures together with catalytic performances of self-supported electrodes are presented and discussed. We also show the specific strategies to further improve the catalytic performance by elemental doping or incorporation of nanocarbons. The simple and one-step methods to fabricate self-supported TMP electrodes are also highlighted. Finally, the challenges and perspectives for self-supported TMP electrodes in water splitting application are briefly discussed.

关键词： transition metal phosphide     self-supported electrode     electrocatalysis     hydrogen evolution reaction    

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现代造纸机的节能与降耗

陈克复,杨旭

《中国工程科学》 2012年 第14卷 第7期   页码 4-8

摘要：

讨论了装备控制先进、车速在准高速以上的现代造纸机实现节能降耗的几个途径，即改进各操作单元的结构、实施先进的关键技术与装备及提高其抄造率和产品成品率来提高整机效率。详细介绍了现代造纸机各操作单元的先进关键技术，以及这些关键技术对节能降耗的作用。通过分析现代造纸机在技术上仍存在的科技难题及我国的实际情况，提出研发国产现代造纸机的车速及幅宽的定位，并对我国研发及生产现代造纸机装备方面提出了合理的建议。

关键词： 节能降耗     现代造纸机     关键技术    

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phosphonate-derived cobalt/nickel phosphide@N-doped carbon hybrids as efficient bifunctional oxygen electrodes

《化学科学与工程前沿（英文）》 2022年 第16卷 第9期   页码 1367-1376 doi: 10.1007/s11705-022-2153-3

摘要： The exploration of efficient bifunctional electrocatalysts for oxygen reduction reaction and oxygen evolution reaction is pivotal for the development of rechargeable metal–air batteries. Transition metal phosphides are emerging as promising catalyst candidates because of their superb activity and low cost. Herein, a novel metal phosphonate-derived cobalt/nickel phosphide@N-doped carbon hybrid was developed by a carbothermal reduction of cobalt/nickel phosphonate hybrids with different Co/Ni molar ratios. The metal phosphonate derivation method achieved an intimately coupled interaction between metal phosphides and a heteroatom-doped carbon substrate. The resultant Co2P/Ni3P@NC-0.2 enables an impressive electrocatalytic oxygen reduction reaction activity, comparable with those of state-of-the-art Pt/C catalysts in terms of onset potential (0.88 V), 4e‒ selectivity, methanol tolerance, and long-term durability. Moreover, remarkable oxygen evolution reaction activity was also observed in alkaline conditions. The high activity is ascribed to the N-doping, abundant accessible catalytic active sites, and the synergistic effect among the components. This work not only describes a high-efficiency electrocatalyst for both oxygen reduction reaction and oxygen evolution reaction, but also highlights the application of metal phosphonate hybrids in fabricating metal phosphides with tunable structures, which is of great significance in the energy conversion field.

关键词： metal phosphonate     cobalt/nickel phosphide     N-doped carbon     oxygen electrochemistry     Zn−air battery    

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标题 作者 时间 类型 操作

Review on cellulose paper-based electrodes for sustainable batteries with high energy densities

期刊论文

Cutting performance of surgical electrodes by constructing bionic microstriped structures

期刊论文

Hollow-fiber gas penetration electrodes efficiently produce renewable synthetic fuels

期刊论文

Research progress on low dielectric constant modification of cellulose insulating paper for power transformers

期刊论文

Technical measures to achieve a cleaner production mode for recycled paper mills

Chao HE, Zhaolin GU, Shucheng YANG, Jidong LIANG, Weina DAI, Yanling HE

期刊论文

Investigation of electrochemical degradation and application of e-paper dyes in organic solvents

Luhai LI, Ming WANG, Yi FANG, Shunan QIAO

期刊论文

Easily-manufactured paper-based materials with high porosity for adsorption/separation applications in

期刊论文

Ultrafast-laser-treated poly(3,4-ethylenedioxythiophene): poly(styrenesulfonate) electrodes with enhanced

期刊论文

论文演化图：学术文献多视角结构化检索

Dan-ping LIAO, Yun-tao QIAN

期刊论文

Efficient photoelectrochemical oxidation of rhodamine B on metal electrodes without photocatalyst or

Xuejiao Wang, Xiang Feng, Jing Shang

期刊论文

Electrospun porous carbon nanofibers derived from bio-based phenolic resins as free-standing electrodes

期刊论文

Performance of activated carbon coated graphite bipolar electrodes on capacitive deionization method

Hossein D. Atoufi, Hasti Hasheminejad, David J. Lampert

期刊论文

Self-supported transition metal phosphide based electrodes as high-efficient water splitting cathodes

Yan Zhang, Jian Xiao, Qiying Lv, Shuai Wang

期刊论文

现代造纸机的节能与降耗

陈克复,杨旭

期刊论文

phosphonate-derived cobalt/nickel phosphide@N-doped carbon hybrids as efficient bifunctional oxygen electrodes

期刊论文